The aim of this paper is to estimate syntectonic P-T conditions within albite- and garnet-bearing orthogneisses. These rocks are generally characterized by the assemblage quartz + albite + biotite + phengite + CaFe-garnet + epidote + titanite. Garnet contains up to 55 mole per cent of grossular. K-feldspar is a relict magmatic phase.
P-T conditions are estimated using several independent methods. First, it is shown that exchange reactions based on the Fe---Mg partitioning between garnet and biotite or garnet and phengite cannot be used to estimate temperatures in these rocks, due to the high grossular content of garnet. Second, maximum and minimum pressures are constrained, respectively, by the occurrence of albite instead of jadeite + quartz and by the assemblage phengite + biotite + quartz. Third, phase equilibria in albite- and garnet-bearing metagranites are modelled in the system K2O---CaO---FeO---Al2O3---SiO2---H2O. Equilibrium curves are calculated for the observed phase compositions. Uncertainties in P-T estimates mainly result from the choice of appropriate non-ideal solution models for the garnet.
An application is developed for granites from the Gran Paradiso nappe (Western Alps). These granites show an heterogeneous deformation of Alpine age expressed by mylonitic shear zones cutting across weakly deformed domains. Estimated P-T conditions for the synkinematic assemblages are 10–16 kbar at 550±50°C. 相似文献
Summary The different functions of cumulative probability of fracture that can be used in the Probabilistic Strength of Materials in the case of constant uniaxial compression are described. Sound fine-grained granite was used to study volume influence by fracturing rectangular prisms, and then no noticeable influence was observed. Since this is showing that all the fracture stresses are belonging to a single set they were included in a single group that exhibited two functions of specific risk of fracture. The population with the lesser fracture stress has no critical zone while the other population does have it and a critical zone in the order of 10–6 m3 is the minimum size exhibiting a complete fracture of the specimen when the same collapses. All the statistical functions were found to be acceptable according to theX2 criterion. 相似文献
Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-3He, 210Po, SO2-and chemical ratios of volatile species in lavas and volcanic gases. These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO2, SO2 and trace metals. They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them. The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction. 相似文献
The central trough of the Bolivian Altiplano is occupied by two wide salt crusts: the salar of Uyuni, which is probably the largest salt pan in the world (10,000 km2) and the salar of Coipasa (2,500 km2). Both crusts are essentially made of porous halite filled with an interstitial brine very rich in Li, K, Mg, B (up to 4.7 g/l Li, 4.3 g/l B, 30 g/l K and 75 g/l Mg). Lithium reserves are the highest known in the world, around 9 × 106 tons. Potassium, magnesium and boron reserves in brines are also important (around 194 × 106 tons K, 8 × 106 tons B and 211 × 106 tons Mg).
The crusts are the remnant of saline Lake Tauca (13,000–10,000 yr BP). Its salinity was estimated approximately at 80 g/l. Its paleochemistry was derived in two ways: (1) by dissolving the present amounts of all chemical components in the former lake volume, and (2) by simulating the evaporation of the major inflows to the basin. The resulting chemical compositions are quite different. The dissolution-derived one is 5 to 50 times less concentrated in Li, K, Mg, B than the evaporation-simulated ones. However all compositions present the same Na and Cl contents. This suggests either a removal of bittern salts or an enrichment of the former lake water in Na and Cl.
The most probable interpretation is that Lake Tauca redissolved a salt crust akin to that existing today. Several older lakes have been detected on the Altiplano. Nevertheless, such an explanation only pushes the problem back. It is likely that the anomaly was transferred from one lake to an other. Three hypotheses may be put forward: (1) bittern seepage through bottom sediments, (2) uptake of the missing components by minerals, and (3) leaching of ancient evaporites from the catchment area at the beginning of the lacustrine history of the basin. The excess halite could have been recycled from lake to lake. This latter process seems to be the most effective to explain the large excess of Na and Cl over the bittern solutes — Li, K, Mg and B. The occurrence of almost pure Na/1bCl saline springs flowing out from a gypsum diapir in the northern Altiplano gives substantial support to this hypothesis. 相似文献
This study presents a comparison of the water vapor and clear-sky greenhouse effect dependence on sea surface temperature for climate variations of different types. Firstly, coincident satellite observations and meteorological analyses are used to examine seasonal and interannual variations and to evaluate the performance of a general circulation model. Then, this model is used to compare the results inferred from the analysis of observed climate variability with those derived from global climate warming experiments. One part of the coupling between the surface temperature, the water vapor and the clear-sky greenhouse effect is explained by the dependence of the saturation water vapor pressure on the atmospheric temperature. However, the analysis of observed and simulated fields shows that the coupling is very different according to the type of region under consideration and the type of climate forcing that is applied to the Earth-atmosphere system. This difference, due to the variability of the vertical structure of the atmosphere, is analyzed in detail by considering the temperature lapse rate and the vertical profile of relative humidity. Our results suggest that extrapolating the feedbacks inferred from seasonal and short-term interannual climate variability to longer-term climate changes requires great caution. It is argued that our confidence in climate models' predictions would be increased significantly if the basic physical processes that govern the variability of the vertical structure of the atmosphere, and its relation to the large-scale circulation, were better understood and simulated. For this purpose, combined observational and numerical studies focusing on physical processes are needed. 相似文献
We use telluric and magnetic data of the diurnal variation recorded in Europe, Australia and North America to study the magnetotelluric tensor in the 6h–24h period range. We use associate directions and we eliminate the effects of deviation of telluric currents. We thus obtain for each observatory reliable phases and apparent resistivity values representative of the neighbouring stratified substratum. It appears that the values obtained in the four European observatories (Saint-Maur, France; Ebro, Spain; Toledo, Spain; Nagycenk, Hungary) give similar results and that these results are different from those obtained either in Tucson (USA) or in Watheroo (Australia).Using Bostick transform we interpret these phase and apparent resistivity values in terms of conductivity of the upper mantle. We discuss then the conductivity heterogeneities in terms of change either in temperature, or partial melting or percentage of fluids of the upper mantle: at depths of about 300 km, the upper mantle appears to be 100 °C hotter under Australia than under Europe; the probable presence of fluids at depths about 100 km in the southwestern North America upper mantle appears to be responsible for the high observed conductivities. All these conductivity values are coherent with tomography results from Woodhouse and Dziewonsky: high (low) conductivities are cohernet with low (high)seismic wave velocities. 相似文献
A detailed isotopic study of the Manaslu leucogranite was carried out. A U-Pb age of 25 Ma and a whole rock Rb-Sr age isochron of 18 Ma were obtained, suggesting that the magmatic activity lasted at least 7 Ma. Initial Sr isotopic ratios are very high (0.740 to 0.760) and initial Nd isotopic ratios are low (
Ndin
: –13 to –16), and they show the existence of large isotopic variations even at the metre scale. These are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes (e.g. fusion, mixing by convection). These results also support the crustal origin of this leucogranite. The Tibetan slab paragneisses, whose Sr and Nd isotopic ratios are very similar to those of the granite at an age of 20 Ma, are the most probable parental material. Nd model ages for both the leucogranite and the gneisses are in the range 1.5–2 Ga. A model of formation of the Manaslu granite by coalescence of different batches of magma is in agreement with the present data. 相似文献
A new method for the sampling of sublimates from high-temperature volcanic gases has been used at Merapi volcano, Java, in 1978. The sublimates were collected on the inner walls of silica tubes introduced into fumarolic vents. Volcanic gases were allowed to move freely through the tubes and as they cooled, a fraction of the volatile components condensed on the inner walls of the tubes along the temperature gradient. The sublimates were then analyzed by a combination of light microscopy, scanning electron microscopy, electron microprobe and X-ray diffraction.Six successive zones of different compositions and mineralogical associations have been identified along the covered range of temperatures (900° to around 400°C). From the high to the low temperatures, these zones are composed of: (1) cristobalite, magnetite, hercynite; (2) molybdenite; (3) acmite; (4) halite, sylvite; (5) sphalerite, pyrite; and (6) galena. Equilibrium calculations show that these crystalline phases are stable for pS2, pC1, and pO2, values typical of magma-buffered gases that have not been contaminated by atmospheric oxygen.The deposits observed in the tubes may be useful in aiding the understanding of the mechanisms acting during the cooling of the gaseous phase on its way to the surface and before its emission into the atmosphere. 相似文献
Volcanic contribution to the atmosphere can be re-evaluated as 5×107 ton/year of CO2, which is less than recent industrial contribution. Degassing is more abundant from volcanoes where magma convections are significant. Effective degassing occurs before the magma reaches the surface, that is, when the magma is fluid. Volcanic gas in the atmosphere can affect the population or the vegetation around volcanoes. 相似文献
On February 20th, 1979, 142 inhabitants of Dieng Plateau (Indonesia) were asphyxiated by poisonous gases during a mild phreatic eruption. From later fields gas collection and analysis, the casualties are considered to be due to CO2 rich volcanic gases. 相似文献
